Sodium oxide

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Sodium oxide
Sodium oxide
General
Systematic name Sodium oxide
Other names Disodium oxide,
soda
Molecular formula Na2O
Molar mass 61.979
Appearance White solid
CAS number [1313-59-3]
Properties
Density and phase 2.270 g/cm3
Solubility in water Decomposes
Other solvents Insolubility
Melting point 1132 °C
Boiling point Decomposes at 1950 °C
Structure
Coordination
geometry
8-coordinate
Crystal structure cubic
Hazards
MSDS External MSDS
EU classification Corrosive (C)
R-phrases R8, R14, R35
S-phrases S8, S27, S39,
S43, S45
NFPA 704

0
3
1
 
Flash point Non-flammable
Supplementary data page
Structure and
properties
n, εr, etc.
Thermodynamic
data
Phase behaviour
Solid, liquid, gas
Spectral data UV, IR, NMR, MS
Except where noted otherwise, data are given for
materials in their standard state (at 25 °C, 100 kPa)
Infobox disclaimer and references

Sodium oxide is a chemical compound with the formula Na2O. It is used in ceramics and glasses. Like most metal oxides, Na2O can exists only as the pure material - it cannot be dissolved in any solvent without reacting irreversibly. For example, treatment with water affords sodium hydroxide.

Na2O + H2O → 2 NaOH

The alkali metal oxides M2O (M = Na, K, Rb) crystallise in the antifluorite structure. In this motif the positions of the anions and cations are reversed relative to their positions in CaF2.[1]

Contents

Typically, glass contains around 15% sodium oxide, the other components being silicon dioxide and calcium oxide at around 70% and 9% respectively. The soda serves as a flux to lower the temperature at which the silica melts. Soda glass has a lower melting temperature vs pure silica and has improved mechanical properties due to the its slightly increases elasticity. These changes arise because the silicon dioxide and soda react to form sodium silicates of the general formula Na2[SiO2]x[SiO3].

Na2O forms when sodium is treated with oxygen.

4 Na + O2 → 2 Na2O

  1. ^ Wells, A.F. (1984) Structural Inorganic Chemistry, Oxford: Clarendon Press. ISBN 0-19-855370-6.

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