Methyl orange

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Methyl orange
Structural formula of methyl orange

3D structure of methyl orange
Systematic name p-dimethylamino-
azobenzenesulfonic acid
Chemical formula C14H15N3O3S
Molecular mass 305.35 g/mol
Density 1.28 g/cm3
Melting point 102.6 °C
Boiling point 102.7 °C
CAS number [547-58-0]
SMILES CN(C)C(C=C2)=CC=C2N=N
C1=CC=C(S(=O)(O[Na])=O)C=C1
pKa 3.39
Disclaimer and references

Methyl Orange is a pH indicator frequently used in titrations.

It is often chosen to be used in titrations because of its clear colour change. Because it changes colour as a mid-strength acid, it is usually used in titrations for acids. Unlike a universal indicator, methyl orange does not have a full spectrum of colour change, but has a sharper end point.


Methyl orange (pH indicator)
below pH 3.1 above pH 4.4
3.1 4.4
Methyl orange in xylene cyanole solution (pH indicator)
below pH 3.2 above pH 4.2
3.2 4.2

In a solution becoming less acidic, methyl orange moves from red to orange and finally to yellow with the reverse occurring for a solution increasing in acidity. It should be noted that the entire color change occurs in acidic conditions. It is actually a green colour

Basically in an acid it is reddish and in alkali it is yellow.

  • Modified methyl orange, an indicator consisting of a solution of methyl orange and xylene cyanol, changes from gray to green as the solution becomes more basic.
  • Phenolphthalein is another indicator frequently used in acid-base titration reactions because of its very sharp color change.
  • A number of other common indicators are tabulated in the article on pH indicators.

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